From Captain Marvel: "The Amazing Trip Into Time" by C.C. Beck, Whiz Comics #26 (January 1942)
In this story, the Big Red Cheese time-travels to the days of America's Found Fathers and Ben Franklin shoots him in the chest with his musket. That's just how they rolled in 1780! (Still 11 years away from ratifying the 2nd Amendment, but Ben was already packing.)
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